Set the oven to preheat at 375°F (190°C).
Generously season both sides of each pork chop with salt and pepper.
Warm the olive oil in a large oven-safe skillet over medium-high heat. Place the pork chops in the skillet and sear for 3 to 4 minutes per side until a golden-brown crust forms.
In a separate bowl, combine the maple syrup, Dijon mustard, apple cider vinegar, garlic powder, and smoked paprika, whisking until the mixture is smooth and well blended.
Drizzle the prepared maple glaze over the pork chops, turning them gently to ensure an even coating.
Move the skillet to the oven and bake for 15 to 20 minutes, or until a thermometer inserted into the thickest part of the pork chops registers 145°F (63°C).
Remove from the oven and allow the meat to rest for a few minutes before plating and serving.